Interesting info re: caliper piston material
“I have been interested in caliper pistons for some time now and have been looking at the parts available in the market and tried to reach some conclusions about the 'best' materials.
To start with I think it is important to review the objectives we have with regard to the duty of the brakes and what is required from the pistons.
There is a view that the 'job' of a caliper seal is not only to prevent fluid leakage but to retract the piston when pressure is released as this stops the pad from rubbing on the disc and is good for economy.
I have to say that I don't agree with this analysis and that pad retraction is generally a bad thing and that the effect of this action is similar to 'pad knock off' and increases pedal travel.
It is common to fit race calipers with either residual springs behind the pistons or with low pressure check valves to eliminate this problem.
The seal is always responsible for a small amount of piston retraction and this will vary depending on the surface finish of the piston, the stored energy in the seal due to radial compression and even the fluid used to lubricate the piston during initial assembly.
Using brake fluid, for example, increases seal friction compared to the correct assembly grease and this influence will last for many thousands of miles.
I believe that good quality pistons should have a high level of surface finish, relatively low thermal coefficient of expansion(TCE), Have relatively low Heat Transfer Coefficient (HTC),be relatively corrosion resistant and have good wear resistance.
If we review the materials that have been discussed then the basic properties are easy to find but there are influences that also need to be considered .
1. Conventional Steel
Typically chrome plated, modest expansion, modest heat transfer, huge amounts of comparative test data available and in every sense have stood the test if time.
A conventional medium carbon steel in an 'as rolled' condition is unlikely to have adequate wear resistance.
The quality in terms of dimensional control and surface finish of some aftermarket parts is questionable but Porsche Caliper Pistons supplied by BudWeg seem to be reasonable and do a good job.
2. Aluminium
As discussed many modern caliper use Aluminium Alloy pistons.
They are easy to manufacture, relatively light and hence quite low cost.
The down side is that they expand more than a conventional steel piston TCE is around twice that of conventional steel , they transfer heat easily into the brake fluid HTC is 5 times greater than conventional steel.
They also don't wear very well unless they are hard anodised. This means that they will need to be centreless ground after anodising as the increase in surface roughness caused by this process will make the piston grab the seal and significantly increase piston retraction.
Modern multi-piston calipers with substantially thick pads clearly cope with pistons of this type but old-fashioned designs which have higher caliper piston temperatures may not do quite so well.
My concern with Aluminium pistons and old fashioned calipers concerns the clearance change when the piston expands.
If the piston has an identical size to the steel piston it replaces then as it heats it will increase the radial compression. This will increase pad retraction and in the limit the piston could stick if temperatures became very high.
If cold clearance is increased to eliminate this issue then seals may wear quite quickly if the car is driven gently and the brakes not heated to provide the optimum value.
This is possibly only an issue for race or trackday cars that are hard driven.
I would admit to never have used any aluminium pistons in early 911 calipers.
3. Stainless Steel
This type of piston is typically manufactured from EN303 which is a free-machining Austenitic Stainless Steel and will provide a high standard of surface finish without centreless grinding and good corrosion resistance.
Its HTC is about one third that of conventional steel so the rate at which the brake fluid heats will be slower and this could be a benefit on a race car.
The problem with Austenitic Stainless Steel is that its TCE is similar to Aluminium so it expands by around 70% more than conventional steel and the same seal issues that concern me for Aluminium will not differ greatly for EN303.
There are Martensitic Stainless Steels available but these don't machine as well and would need grinding. The TCE would, however, be the same as conventional steel.
We did buy a batch of Stainless Steel Pistons from a supplier in the USA and had very mixed results. (20 Caliper sets)
Many or them worked well in normal road cars but about 50% of the ones fitted to Race cars stuck during high speed practice and did cause us some difficulty.
This problem is what caused us to look more closely at these issues.
4. Titanium
There are several grades of Titanium available in the market place and the traditional 6AL4V Grade 5 material is the optimum choice.
This alloy has excellent strength, it has a very low HTC - 50% lower than Austenitic Stainless Steel so about 6 times lower than Conventional Steel and 30 times lower than aluminium.
Its TCE is about the same as conventional steel (within 5%) so all seal behaviour should be identical to the original part.
Apart form cost it looks like a good material but it is prone to wear in rubbing seal applications.
The fix for this is to coat the piston and the typical finish is to use a Titanium Carbide applied in a PVD chamber.
This finish is as hard as DLC and provides an extremely smooth surface.
5. Phenolic Resin
This material can be quite hard and have virtually zero HTC but depending on the filler does expand about 4 time more than even aluminium.
It will absorb water and loose strength so the part of the piston outside the dust bot could deteriorate.
I am sure that some materials such as Torlon may work but for small aftermarket quantities the testing needed to be 100% confident would be huge and difficult to justify.
5. Silicon Nitride
It is possible to place silicon Nitride plugs into the cavity in the piston and these will insulate but I have never tired this idea and I am not sure about how 'square' this arrangement would be in practice.
We eventually decided to make our own 6AL4V Titanium Pistons.
they are manufactured on our behalf by a sub-contractor who manufactures pistons for AP Racing.
They are centreless ground polished and Titanium carbide coated and seem to work well.
Sorry to bang on but I hope some detail was worthwhile.”
From:
Because of this? Mine had surface rust around the semi-perimeter and also inside the dome. Is this normal ?
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